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131.
132.
The three GC coeluting C40 bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C21–C24 series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C40 isoprenoids. The C21–C24 quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards. 相似文献
133.
Molybdenum concentrations in Icelandic geothermal waters lie in the range 1–70 ppb. Warm waters and dilute high-temperature waters which contain high concentrations of sulphide are lowest in molybdenum. No correlation is otherwise observed between molybdenum concentrations and temperature. Surface waters and cold ground waters do not contain detectable molybdenum (<1 ppb). It seems likely that leaching rate is the prime factor in limiting molybdenum levels in these waters. Within individual geothermal fields molybdenum concentrations are either approximately constant or they vary regularly across the field. This regular variation may often be correlated with variations in other solute concentrations and subsurface temperatures and is taken to indicate a control of molybdenum mobility by a temperature dependent equilibrium. The evidence suggests that the solubility of molybdenite is responsible. Molybdenite has not been found in active geothermal systems in Iceland but is known to occur in some New Zealand geothermal systems and it has been identified in hydrothermally altered Tertiary basalt formations at Reydarártindur in southeast Iceland. Boiling and mixing with cold water leads to molybdenite undersaturation and thus these processes favour leaching of molybdenum from the rock. On the other hand, conductive cooling leads to supersaturation which favours removal of molybdenum from solution. 相似文献
134.
Stefán Arnórsson 《Geochimica et cosmochimica acta》1984,48(12):2489-2502
Germanium concentrations in geothermal waters in Iceland lie mostly in the range 2–30 ppb. There is an overall positive relation between the germanium content of the water and its temperature. Most of the germanium occurs as Ge(OH)?5in solution but Ge(OH)4 may also be present in significant amounts in saline waters when above 200°C. Evidence indicates that aqueous germanium concentrations are controlled by exchange reactions where it substitutes for silica in silicates and iron in sulphides. It is the rate of dissolution and the relative abundance of the alteration minerals which take up germanium to a variable extent that ultimately fix Ge(OH)4 concentrations in the water. This, together with water pH, fixes total dissolved germanium. It is mostly the primary rock composition that dictates the relative abundance of the alteration minerals. Conductive cooling in upflow zones favours removal of germanium from solution. During the initial stages of boiling of rising hot water dissolution is enhanced but precipitation at later stages.Thermodynamic data of various aqueous germanium species and several minerals are summarized and dissociation constants and solubilities estimated at elevated temperatures using available predictive methods. 相似文献
135.
Kristín Vala Ragnarsdóttir John V Walther Stefán Arnórsson 《Geochimica et cosmochimica acta》1984,48(7):1535-1553
The bulk composition and mineralogy of hydrothermally altered tholeiite, along with the composition and speciation of fluid, have been determined for a well-defined alteration zone at 240°C and 110 bars at Svartsengi, Iceland. Mass balances between the geothermal fluid and altered tholeiite, relative to a seawater/fresh water mixture and unaltered tholeiite, indicate the overall reaction per 1000 cm3 is: 1325 gm plagioclase + 1228 gm pyroxene + 215 gm oxide-minerals break down to form 685 gm chlorite + 636 gm albite + 441 gm quartz + 249 gm epidote + 266 gm calcite + 201 gm oxide-minerals + 15 gm pyrite, requiring an influx of 123 gm CO2, 10 gm H2S and 4 gm Na2O and a release of 57 gm SiO2, 35 gm FeO, 21 gm CaO, 8 gm MgO and 4 gm K2O.Principal reactions, deduced from textural evidence, include Na-Ca exchange in plagioclase, precipitation of quartz, calcite and anhydrite, and formation of chlorite and epidote by reactions between groundmass minerals and fluid.Thermodynamic analyses of authigenic minerals and downhole fluid indicate that the fluid maintains a state close to equilibrium with the secondary mineral phases chlorite, epidote, albite, quartz, calcite, prehnite, anhydrite, pyrite and magnetite, whereas remnant primary labradorite and augite are out of equilibrium with the fluid.Water/rock ratios for the system are determined under a variety of assumptions. However, the open nature of the system makes comparisons with experimental and theoretical closed system studies ambiguous. 相似文献
136.
József Ádám 《Journal of Geodesy》1982,56(3):180-195
The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections
on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations”
and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean
space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and
“condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some
familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least
squares adjustment are elegant and powerful geodetic methods. 相似文献
137.
138.
We report normalized AF demagnetization curves of anhysteretic remanences (ARM's) produced by 1-, 10- and 40-Oe steady fields and of saturation isothermal remanence (IRMs) in a suite of dispersed, unannealed magnetite powders with median sizes of 2, 4, 6, 10 and 14 μm (pseudo-single-domain or PSD size range) and 100 μm (multidomain or MD size). Interpreted in the light of the domain structure test first proposed by Lowrie and Fuller [12], the relative stability trend of curves for the 2 μm sample is of single-domain (SD) type, the 1-Oe ARM being most resistant to demagnetization followed by the 10-Oe and 40-Oe ARM's and IRMs. For the 100-μm sample, the trend is exactly reversed and is of MD-type. In the 4–14 μm samples, hitherto undescribed transitional trends between SD-type and MD-type occur. At 6 μm, 1-Oe, 10-Oe and 40-Oe ARM's preserve an SD-type trend but for all AF's > 75 Oe, IRMs is more resistant than any of these remanences. At 10 μm, this trend is unmistakable, and only at 14 μm do the 1-Oe, 10-Oe and 40-Oe ARM curves merge. We conclude (1) that the Lowrie-Fuller test distinguishes between small MD grains enhanced by PSD remanence and large MD grains lacking PSD remanence, rather than between SD and MD structures per se, and (2) that in the PSD transition region from 6 to 14 μm in magnetite, IRMs changes over to MD-type relative stability around 6 μm, whereas 10-Oe and 40-Oe ARM's achieve an MD-type trend around 14 μm, in accord with the predicted field dependence of the PSD threshold size.Our theoretical interpretation assumes that the intrinsic (internal field) coercive force spectra of weak-field and strong-field remanences are identical but that the observed (external field) spectrum is shifted to lower fields as a result of the internal demagnetizing field — NJr of the remanence Jr. The effect is slight for weak-field Jr's but substantial for IRMs. Since all coercivities, high as well as low, are shifted, the result of the Lowrie-Fuller test is determined simply by the shape of the intrinsic coercivity spectrum or the corresponding AF demagnetization curve. Depending on the model of self-demagnetization used, either subexponential or sublinear AF decay curves of weak-field remanence will automatically lead to an MD-type trend, whereas by either model the decay curves that characterize SD and PSD remanences (decaying slowly initially and then more rapidly) will always produce and SD-type trend. 相似文献
139.
Stefán Arnórsson Einar Gunnlaugsson Hördur Svavarsson 《Geochimica et cosmochimica acta》1983,47(3):567-577
New data from geothermal wells in Iceland have permitted empirical calibration of the chalcedony and geothermometers in the range of 25–180°C and 25–250°C respectively. The temperature functions are: Concentrations are expressed in ppm. These temperature functions correspond well with the chalcedony solubility data of Fournier (1973) and the thermodynamic data for low-albite/microcline/solution equilibria of Heloeson (1969).A new CO2 geothermometer is proposed which is considered to be useful in estimating underground temperatures in fumarolic geothermal fields. Its application involves analysis of CO2 concentrations in the fumarole steam. The temperature function which applies in the range 180?300°C is: logCO2 = 37.43 + 73192/T- 11829· 103/T2 + 0.18923T- 86.187·logT where T is in °K and CO2 in moles per kg of steam. 相似文献
140.
A.E. Jennings S. Hagen J. Harðardóttir R. Stein A.E.J. Ogilvie I. Jónsdóttir 《Climatic change》2001,48(1):83-100
Environmental proxies of soil erosion on Iceland, and oceanographic conditions on the adjacent shelf, were measured on a 50 cm box core taken from the southwest Iceland shelf in 1993 during cruise 93030 of the Canadian ship, CSS Hudson. These data, covering the last several centuries, are compared with the documentary record of sea-ice changes around Iceland since A.D. 1600. The site is under the influence of the Irminger Current, which carries warm, saline, Atlantic water northward along the shelf. Because of the relative warmth of this current, sea ice rarely occurs off southwest Iceland, even during the most severe sea-ice intervals of the historical record. In severe sea-ice years, however, the ice drifts clockwise around Iceland from the northeast and east and, in rare cases, reaches the southern coasts (Ogilvie, 1992). The chronology of the core was established by converting the basal radiocarbon date to calendar years and assuming a linear sedimentation rate from the base of the core to the year of collection, 1993. Organic carbon, stable C and O isotope ratios, planktonic foraminiferal assemblages, and sediment magnetic parameters were measured on samples from the core, plotted against calendar years and compared to the Icelandic sea-ice index. The environmental proxies suggest that increased soil erosion, reduced salinity, and, possibly, decreased marine productivity prevailed during the severe sea-ice interval lasting from the last quarter of the eighteenth century to around 1920. Such a situation could develop with climatic cooling, increased storminess, and loss of vegetation cover to stabilise the soil. Although the core site generally lies outside the sea-ice limits, the evidence clearly shows the influence of sea ice and fresh water, and is sensitive to the overall climatic deterioration manifested by the sea-ice record. 相似文献